Colloidal synthesis and magnetic properties of anisotropic-shaped spinel CuCr2Se4 nanocrystals

نویسندگان

  • Chao Pang
  • Ruiqiang Yang
  • Amit Singh
  • Hanjiao Chen
  • Michael K. Bowman
  • Ningzhong Bao
  • Liming Shen
  • Arunava Gupta
چکیده

Anisotropic-shaped CuCr2Se4 nanocrystals have been synthesized by thermal decomposition and reaction of novel mixedmetal–oleate complexes with selenium in a high-boiling point organic solvent, trioctylamine (TOA). The synthesized CuCr2Se4 nanocrystals exhibit close to triangular and hexagonal morphology, with an average size of 20 nm. X-ray diffraction patterns and XPS spectral analysis confirm the formation of the pure spinel phase without any impurities. A possible reaction mechanism is suggested and formation pathways for the triangular and hexagonal shaped CuCr2Se4 nanocrystals are proposed. Magnetic studies indicate that the anisotropic-shaped CuCr2Se4 nanocrystals are superparamagnetic near room temperature but exhibit ferromagnetic behavior at lower temperatures, with magnetization values of 31 and 43 emu g 1 at 300 and 5 K, respectively.

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تاریخ انتشار 2017